Some Basic Concepts of Chemistry 2 Question 20

20. For the redox reaction

$$ \mathrm{MnO}{4}^{-}+\mathrm{C}{2} \mathrm{O}{4}^{2-}+\mathrm{H}^{+} \longrightarrow \mathrm{Mn}^{2+}+\mathrm{CO}{2}+\mathrm{H}_{2} \mathrm{O} $$

The correct coefficients of the reactants for the balanced reaction are

$\mathrm{MnO}_{4}^{-}$ $\mathrm{C}{2} \mathrm{O}{4}^{2-}$ $\mathrm{H}^{+}$
(a) 2 5 16
(b) 16 5 2
(c) 5 16 2
(d) 2 16 5

(1992)

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Solution:

  1. The balanced redox reaction is :

$$ 2 \mathrm{MnO}{4}^{-}+5 \mathrm{C}{2} \mathrm{O}{4}^{2-}+16 \mathrm{H}^{+} \longrightarrow 2 \mathrm{Mn}^{2+}+10 \mathrm{CO}{2}+16 \mathrm{H}_{2} \mathrm{O} $$

Hence, the coefficients of reactants in balanced reaction are 2, 5 and 16 respectively.