Solutions and Colligative Properties 2 Question 24

24. Which of the following $0.1 \mathrm{M}$ aqueous solution will have the lowest freezing point?

(1989, 1M)

(a) Potassium sulphate

(b) Sodium chloride

(c) Urea

(d) Glucose

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Solution:

  1. $\mathrm{K}{2} \mathrm{SO}{4}: \quad i=3$

$\mathrm{NaCl}: \quad i=2$

Urea : $i=1$

Glucose : $i=1$

Greater the value of $i$, greater the lowering in freezing point, lower will be the freezing temperature, if molarity in all cases are same. Therefore, $\mathrm{K}{2} \mathrm{SO}{4}$ solution has the lowest freezing point.