pBlock ElementsII 2 Question 18

18. $\mathrm{KF}$ combines with $\mathrm{HF}$ to form $\mathrm{KHF}_{2}$. The compound contains the species

(1996, 1M)

(a) $\mathrm{K}^{+}, \mathrm{F}^{-}$and $\mathrm{H}^{+}$

(b) $\mathrm{K}^{+}, \mathrm{F}^{-}$and $\mathrm{HF}$

(c) $\mathrm{K}^{+}$and $\left[\mathrm{HF}_{2}\right]$

(d) $[\mathrm{KHF}]^{+}$and $\mathrm{F}^{-}$

Show Answer

Solution:

  1. All others has at least one S-S linkage.

$$ \mathrm{KF}+\mathrm{HF} \longrightarrow \mathrm{K}^{+}+\mathrm{HF}_{2}^{-} $$