pBlock ElementsII 1 Question 50

50. Nitrogen (I) oxide is produced by

(a) thermal decomposition of $\mathrm{NH}{4} \mathrm{NO}{3}$

(b) disproportionation of $\mathrm{N}{2} \mathrm{O}{4}$

(c) thermal decomposition of $\mathrm{NH}{4} \mathrm{NO}{2}$

(d) interaction of hydroxylamine and nitrous acid

Numerical Value

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Solution:

  1. $\mathrm{NH}{4} \mathrm{NO}{3} \xrightarrow{\text { Heat }} \mathrm{N}{2} \mathrm{O}+2 \mathrm{H}{2} \mathrm{O}$

$\mathrm{NH}{2} \mathrm{OH} \cdot \mathrm{HCl}+\mathrm{NaNO}{2} \longrightarrow \mathrm{NaCl}+2 \mathrm{H}{2} \mathrm{O}+\mathrm{N}{2} \mathrm{O}$

However, $\mathrm{NH}{4} \mathrm{NO}{2}$ on heating gives $\mathrm{N}_{2}$.