Organic Chemistry Basics 2 Question 18

18. Arrange the following compounds in the order of decreasing acidity

(2013 Main)

(a) II $>$ IV $>$ I $>$ III

(b) I $>$ II $>$ III $>$ IV

(c) III $>$ I $>$ II $>$ IV

(d) IV $>$ III $>$ I $>$ II

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Solution:

18.

(III)

(I)

(II)

(IV)

Electron releasing group decreases while electron withdrawing group increases acidic strength by destabilising and stabilising the phenoxide ion formed respectively.