Organic Chemistry Basics 2 Question 12

12. Which of the following molecules is least resonance stabilised?

(2017 Main) (a)

(b)

(c)

(d)

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Answer:

Correct Answer: 12. (d)

Solution:

  1. Aromatic compounds are stable due to resonance while non-aromatics are not. According to Huckel’s rule (or $4 n+2$ rule), “For a planar, cyclic compound to be aromatic, its $\pi$ cloud must contain $(4 n+2) \pi$ electrons, where, $n$ is any whole number.” Thus,

are aromatic and stabilised by resonance.

They follow Huckel’s rule.

is non-aromatic, hence, least stabilised by resonance.