Carboxylic Acids and their Derivatives 2 Question 43

43. Which of the following carboxylic acids undergoes decarboxylation easily? Explain briefly.

(i) $\mathrm{C}{6} \mathrm{H}{5} \mathrm{COCH}_{2} \mathrm{COOH}$

(ii) $\mathrm{C}{6} \mathrm{H}{5} \mathrm{COCOOH}$

(iii) $\mathrm{C}{6} \mathrm{H}{5} \mathrm{CH}(\mathrm{OH}) \mathrm{COOH}$

(iv) $\mathrm{C}{6} \mathrm{H}{5} \mathrm{CH}\left(\mathrm{NH}_{2}\right) \mathrm{COOH}$

$(1995,2 M)$

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Solution:

  1. A $\beta$-keto acid undergo very fast decarboxylation