Carboxylic Acids and their Derivatives 2 Question 31

31. The total number of carboxylic acid groups in the product $P$ is

(2013 Adv.)

Subjective Questions

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Solution:

  1. PLAN eactant is cyclic anhydride and chan es to dicarboxylic acid on hydrolysis.

Also there is decarboxylation on heating if there is keto group w.r.t $-\mathrm{COOH}$ group. Ozonolysis cleaves $(\mathrm{C}=\mathrm{C})$ bond and $\mathrm{H}{2} \mathrm{O}{2}$ oxidises - $\mathrm{CHO}$ to $-\mathrm{COOH}$ group.

Anhydride

Thus, number of $-\mathrm{COOH}$ groups in $P=2$.