Carboxylic Acids and their Derivatives 2 Question 26

26. Which is the rate determining step in Hofmann’s bromamide degradation?

(a) Formation of (i)

(b) Formation of (ii)

(c) Formation of (iii)

(d) Formation of (iv)

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Solution:

  1. Rearrangement of (iii) to (iv) is the rate determining step :

(iii)

(iv)