Carboxylic Acids and their Derivatives 2 Question 15

15. Acetamide is treated separately with the following reagents. Which one of these would give methyl amine?

$(1983,1 \mathrm{M})$

(a) $\mathrm{PCl}_{5}$

(b) $\mathrm{NaOH}+\mathrm{Br}_{2}$

(c) Sodalime

(d) Hot conc. $\mathrm{H}{2} \mathrm{SO}{4}$

Objective Questions I

(One or more than one correct options)

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Answer:

Correct Answer: 15. $(\mathrm{a}, \mathrm{c})$

Solution:

  1. $\mathrm{CH}{3}-\mathrm{C}-\mathrm{NH}{2}+\mathrm{Br}{2}+\mathrm{NaOH} \longrightarrow \mathrm{CH}{3} \mathrm{NH}_{2}$ “Hofmann’s bromamide reaction”.