Atomic Physics Question 4

Question 4 - 2024 (27 Jan Shift 2)

If Rydberg’s constant is $\mathrm{R}$, the longest wavelength of radiation in Paschen series will be $\frac{\alpha}{7 R}$, where $\alpha=$

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Answer: (144)

Solution:

Longest wavelength corresponds to transition between $\mathrm{n}=3$ and $\mathrm{n}=4$

$\frac{1}{\lambda}=\mathrm{RZ}^{2}\left(\frac{1}{3^{2}}-\frac{1}{4^{2}}\right)=\mathrm{RZ}^{2}\left(\frac{1}{9}-\frac{1}{16}\right)$

$=\frac{7 \mathrm{RZ}^{2}}{9 \times 16}$

$\Rightarrow \lambda=\frac{144}{7 \mathrm{R}}$ for $\mathrm{Z}=1 \quad \therefore \alpha=144$