Thermodynamics C Question 3

Question 3 - 2024 (27 Jan Shift 1)

If three moles of an ideal gas at $300 \mathrm{~K}$ expand isotherrnally from $30 \mathrm{dm}^{3}$ to $45 \mathrm{dm}^{3}$ against a constant opposing pressure of $80 \mathrm{kPa}$, then the amount of heat transferred is _______ J.

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Answer (1200)

Solution

Using, first law of thermodynamics,

$\Delta \mathrm{U}=\mathrm{Q}+\mathrm{W}$,

$\Delta \mathrm{U}=0$ : Process is isothermal

$\mathrm{Q}=-\mathrm{W}$

$\mathrm{W}=-\mathrm{P}_{\text {ext }} \Delta \mathrm{V}:$ Irreversible

$=-80 \times 10^{3}(45-30) \times 10^{-3}$

$=-1200 \mathrm{~J}$