Coordination Compounds Question 6

Question 6 - 2024 (27 Jan Shift 2)

Identify from the following species in which $\mathrm{d}^{2} \mathrm{sp}^{3}$ hybridization is shown by central atom:

(1) $\left[\mathrm{Co}\left(\mathrm{NH}{3}\right){6}\right]^{3+}$

(2) $\mathrm{BrF}_{5}$

(3) $\left[\mathrm{Pt}(\mathrm{Cl})_{4}\right]^{2-}$

(4) $\mathrm{SF}_{6}$

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Answer (1)

Solution

$\left[\mathrm{Co}\left(\mathrm{NH}{3}\right){6}\right]^{+3}-\mathrm{d}^{2} \mathrm{sp}^{3}$ hybridization

$\mathrm{BrF}_{5}-\mathrm{sp}^{3} \mathrm{~d}^{2}$ hybridization

$\left[\mathrm{PtCl}_{4}\right]^{-2}-\mathrm{dsp}^{2}$ hybridization

$\mathrm{SF}_{6}-\mathrm{sp}^{3} \mathrm{~d}^{2}$ hybridization