Coordination Compounds Question 2

Question 2 - 2024 (01 Feb Shift 1)

Which of the following complex is homoleptic?

(1) $\left[\mathrm{Ni}(\mathrm{CN})_{4}\right]^{2-}$

(2) $\left[\mathrm{Ni}\left(\mathrm{NH}{3}\right){2} \mathrm{Cl}_{2}\right]$

(3) $\left[\mathrm{Fe}\left(\mathrm{NH}{3}\right){4} \mathrm{Cl}_{2}\right]^{+}$

(4) $\left[\mathrm{Co}\left(\mathrm{NH}{3}\right){4} \mathrm{Cl}_{2}\right]^{+}$

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Answer (1)

Solution

In Homoleptic complex all the ligand attached with the central atom should be the same. Hence $\left[\mathrm{Ni}(\mathrm{CN})_{4}\right]^{2-}$ is a homoleptic complex.