Coordination Compounds Question 16

Question 16 - 2024 (31 Jan Shift 1)

The correct statements from following are:

A. The strength of anionic ligands can be explained by crystal field theory.

B. Valence bond theory does not give a quantitative interpretation of kinetic stability of coordination compounds.

C. The hybridization involved in formation of $\left[\mathrm{Ni}(\mathrm{CN})_{4}\right]^{2-}$ complex is dsp ${ }^{2}$.

D. The number of possible isomer(s) of cis- $\left[\mathrm{PtCl}{2}(\mathrm{en}){2}\right]^{2+}$ is one

Choose the correct answer from the options given below:

(1) A, D only

(2) A, C only

(3) B, D only

(4) B, C only

Show Answer

Answer (4)

Solution

B. VBT does not explain stability of complex

C. Hybridisation of $\left[\mathrm{Ni}(\mathrm{CN})_{4}\right]^{-2}$ is $\mathrm{dsp}^{2}$.