P Block Elements Group 13 Question 3

Question 3 - 29 January - Shift 2

Given below are two statements:

Statement I : The decrease in first ionization enthalpy from $B$ to $Al$ is much larger than that from $Al$ to $Ga$.

Statement II : The d orbitals in Ga are completely filled.

In the light of the above statements, choose the most appropriate answer from the options given below

(1) Statement I is incorrect but statement II is correct.

(2) Both the statements I and II are correct

(3) Statement I is correct but statement II is incorrect

(4) Both the statements I and II are incorrect

Show Answer

Answer: (2)

Solution:

Formula: Trend in Ionization Enthalphy

The first ionization energies (as in NCERT) are as follows:

B : $801 kJ / mol$

$Al: 577 kJ / mol$

$Ga: 579 kJ / mol$

$Ga:[Ar] 3 d^{10} 4 s^{2} 4 p^{1}$