Ionic Equilibrium Question 3

Question 3 - 25 January - Shift 1

A litre of buffer solution contains 0.1 mole of each of $NH_3$ and $NH_4 Cl$. On the addition of 0.02 mole of $HCl$ by dissolving gaseous $HCl$, the $pH$ of the solution is found to be $\times 10^{-3}$ (Nearest integer)

[Given : $pK_b(NH_3)=4.745$

$\log 2=0.301$

$\log 3=0.477$

$T=298 K]$