JEE Main On 8 April 2017 Question 30

Question: A metal ‘M’ reacts with nitrogen gas to afford $ ‘M _3N’.‘M _3N’ $ on heating at high temperature gives back ‘M’ and on reaction with water produces a gas ‘B’. Gas ‘B’ reacts with aqueous solution of $ CuSO _4 $ to form a deep blue compound. ‘M’ and ‘B’ respectively are : [JEE Online 08-04-2017]

Options:

A) Li and $ NH _3 $

B) Na and $ NH _3 $

C) Ba and $ N _2 $

D) Al and $ N _2 $

Show Answer

Answer:

Correct Answer: A

Solution:

  • Li and $NH_3 $

The metal ‘M’ forms nitride M3N. Since N has valency 3, metal ‘M’ has valence 1. Hence, ‘M’ can be either Li or Na. So we can rule out Ba and Al.